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white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">在我國綠色環保理念開展之下，安全健康可持續開展的理念家喻戶曉，因此在工業范疇開展之中工業廢氣排放與VOCs有機廢氣成為了重要的作業內容之一。VOC是指揮發性有機化合物在常壓下，沸點50℃-260℃的各種有機化合物。是一類毒性大、污染嚴重的化學物質。VOCs種類繁復，來源也十分廣泛，成分復雜，即使同一物質，因為風量不同、濃度不同，所需處理的技能路線也不一樣。很多的企業積極投合我國大氣VOCs有廢氣處理方針，推動揮發性氣體VCOs有機廢氣管理方法著重于提高VOCs有機廢氣處理效果。下文為大家介紹催化焚燒在VCOs廢氣管理中具有哪些功能？</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">國內外VOCs污染操控方法目前首要有吸附法、吸收法、生物處理技能、膜分離技能、直接焚燒法、催化焚燒法等。蓄熱式催化燃燒設備（Regenerative Catalytic Oxidation），簡稱RCO，是近10余年內開展起來的新技能，它的原理是經過廢氣在催化劑下下降其活化能，提高廢氣處理的反響速率，憑借催化劑使用有機廢氣在比較低的起燃溫度下產生氧化分解成H2O跟CO2的進程。起燃溫度低能耗少，凈化率高，適應性強，能耗在焚燒法中低，無二次污染，可直接應用于高濃度（500mg/m3-10000mg/m3）的有機廢氣凈化。</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">1、催化燃燒原理</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">憑借催化劑可使有機廢氣在較低的起燃溫度條件下，產生無焰焚燒，并氧化分解為CO2和H20，一起放出很多熱。</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">2、催化燃燒特點</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">2.1起燃溫度低，反響速率快，節省能源。催化焚燒進程中，催化劑起到下降VOCs分子與氧分子反響的活化能，改動反響途徑的效果。</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">2.2處理效率高，二次污染物和溫室氣體排放量少。選用催化焚燒處理VOCs廢氣凈化率一般在95%以上，終產物首要為CO2和H2O。因為催化焚燒溫度低，很多削減NOx的生成。輔助燃料消耗排放的CO2量在總CO2排放量中占很大比例，輔助能源消耗量削減，明顯削減了溫室氣體CO2排放量。</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">2.3適用規模廣,催化焚燒幾乎能夠處理所有的烴類有機廢氣及惡臭氣體，適合處理的VOCs濃度規模廣。關于低濃度、大流量、多組分而無收回價值的VOCs廢氣，選用催化焚燒法處理是Z經濟合理的。</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">3.催化燃燒工藝流程</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">依據廢氣預熱方法及富集方法，催化焚燒工藝流程可分為3種。</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">(1)預熱式。預熱式是催化焚燒的Z基本流程形式。有機廢氣溫度在100℃以下，濃度也較低，熱量不能自給，因此在進入反響器前需要在預熱室加熱升溫。焚燒凈化后氣體在熱交換器內與未處理廢氣進行熱交換，以收回部分熱量。該工藝一般選用天然氣或電加熱升溫至催化反響所需的起燃溫度。</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">(2)本身熱平衡式。當有機廢氣排出時溫度高于起燃溫度(在300℃左右)且有機物含量較高，熱交換器收回部分凈化氣體所產生的熱量，在正常操作下能夠維持熱平衡，無需彌補熱量，一般只需要在催化焚燒反響器中設置電加熱器供起燃時使用。</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">(3)吸附一催化焚燒。當有機廢氣的流量大、濃度低、溫度低，選用催化焚燒需耗很多燃料時，可先選用吸附手段將有機廢氣吸附于吸附劑上進行濃縮，然后經過熱空氣吹掃，使有機廢氣脫附成為高濃度有機廢氣(可濃縮10倍以上)，再進行催化焚燒。此時，不需要彌補熱源，就可維持正常作業。</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">關于有機廢氣催化焚燒工藝的選擇首要取決于：</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">(1)焚燒進程的放熱量，即廢氣中可燃物的種類和濃度;</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">(2)起燃溫度，即有機組分的性質及催化劑活性;</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">(3)熱收回率等。當收回熱量超過預熱所需熱量時，可完結本身熱平衡作業，無需外界彌補熱源，這是Z經濟的。</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">催化焚燒設備適用于漆包線、機械、電機、化工、外表、汽車、發動機、塑料、電器等行業的有機廢氣凈化，各種烘道、印刷油墨、電機絕緣處理等烘干流水線等。用于有機溶劑的凈化處理如:苯類、醇類、酯類、酚類、醚類、烷類等混合性有機廢氣。廢氣成分中，不能含有下列物質：有高粘性的油脂類。如磷、鉍、砷、銻、汞、鉛、錫；高濃度的粉塵。設備選型時，注明廢氣的成份、濃度及出口溫度，設備裝置場所無腐蝕性氣體，并有杰出的防雨措施，設備所需電源為三相溝通380V，頻率50Hz。</span><span style="font-family: "sans serif", tahoma, verdana, helvetica;">燃燒設備系統作業進程首要劃分為三種狀況參數設定、焚燒作業和焚燒停止。焚燒作業狀況燃空比的調定，催化焚燒時的“燃氣/空氣比值”規模一般在4%～11%之間；在必定的焚燒條件之下，燃/空比為6%時，天然氣就能完結較好的催化焚燒效果，焚燒系統就能夠得到熱效率，一起又能取得較好的排放效果。焚燒起動進程經過紫外線傳感器的檢測到期小火點著后，翻開主燃氣閥門。這時催化焚燒爐盤進行有焰焚燒，直到檢測溫度信號到達設定的焚燒封閉溫度，焚燒閥門封閉，完結焚燒進程，進入到焚燒調節階段。</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">當操控系統在待命的狀況下，接到輸入的起動指令，將進入焚燒作業狀況，先是操控系統進行自檢，之后進行前吹掃，變頻器輸出信號操控風機的旋轉，空氣風量由低速漸變為高速再逐步變為低速，新鮮空氣風吹過焚燒爐盤，以確保爐內沒有殘留燃氣的存在，確保焚燒進程的牢靠。具體操作是變頻器先起動，PLC模擬輸出信號使變頻器頻率從起動設定頻率開端上升，到達必定頻率后堅持必定時刻后再下降，完結起動前的吹掃。之后宣布焚燒信號，高壓焚燒器作業，一起翻開焚燒管道的閥門，小火點著。</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">參數設定狀況，此狀況為焚燒作業之前做好數據的準備?？梢罁枰謩e設定焚燒溫度和變頻器起動時的頻率，操控風機的風量。焚燒溫度是為了確保焚燒進程的牢靠性。起動頻率確保催化焚燒器在剛點著時的有焰焚燒，這時的焚燒比不易太低，風量不能過大。</span><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><br style="font-family: "sans serif", tahoma, verdana, helvetica; font-size: 12px; white-space: normal;"/><span style="font-family: "sans serif", tahoma, verdana, helvetica;">催化焚燒用的是表面具有貴金屬和金屬氧化物的催化劑，將有機污染物的廢氣在催化劑鉑、鈀的效果下，能夠在較低的溫度下將廢氣中的有機污染物氧化成二氧化碳和水。催化劑的參加并不能改動原有的化學平衡，所改動的僅是化學反響的速度，而在反響前后，催化劑本身的性質并不產生變化。催化焚燒設備首要由活性炭吸附箱、阻火器、熱交換器，催化反響床，風機這幾個首要部件組成。與直接焚燒相比，催化焚燒溫度較低，焚燒比較完全。</span></span></p></div> <div class="xypg-detail-tags"> <div class="tags-title"> <h3>標簽</h3> <div class="baidu-share">  <div class="bdsharebuttonbox"> <a href="#" class="bds_more" data-cmd="more"></a> <a href="#" class="bds_tsina" data-cmd="tsina" title="分享到新浪微博"></a> <a href="#" class="bds_weixin" data-cmd="weixin" title="分享到微信"></a> <a href="#" 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